Loss of Hydrogen from Dihydroxyacetone Phosphate during Glyceryl Ether Synthesis
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منابع مشابه
Loss of hydrogen from dihydroxyacetone phosphate during glyceryl ether synthesis.
In order to obtain information on the mechanism of ether bond formation in the synthesis of 0-alkyl lipids, a study was carried out to determine if there is a loss of hydrogen from carbon 3 of dihydroxyacetone phosphate (DHAP) (nonphosphorus-linked carbon) in the course of its incorporation into glyceryl ethers. Accordingly, a mixture of [1,3-3H2] DHAP and [I ,3-WJDHAP was prepared. In a micros...
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A lipid, stable to alkaline methanolysis, is formed when liver mitochondria or brain microsomes are incubated with dihydroxyacetone phosphate, long chain alcohol, ATP, CoA, NaF and Mg*. The lipid has been identified as alkyl dihydroxyacetone phosphate. This lipid is reduced by NADPH to 1-alkyl glycerol3-phosphate and is further acylated to form 1-alkyl 2-acyl glycerol-3-phosphate. The ether-con...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1971
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(18)61879-4